An Expeditious Entry to 9-Azabicyclo[3.3.1]nonane N-Oxyl (ABNO): Another Highly Active Organocatalyst for Oxidation of Alcohols
An Expeditious Entry to 9-Azabicyclo[3.3.1]nonane N-Oxyl (ABNO): Another Highly Active Organocatalyst for Oxidation of Alcohols
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DOI：
10.1021/jo900486w
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发表时间：
2009-06-19
影响因子：
3.6
通讯作者：
Iwabuchi, Yoshiharu
中科院分区：
文献类型：
--
作者：
Shibuya, Masatoshi;Tomizawa, Masaki;Iwabuchi, Yoshiharu
建立了一种实用的三步合成9-氮杂环[3.3.1]壬烷n -氧基（ABNO, 3）的方法。与TEMPO相比，ABNO在催化醇氧化成相应羰基化合物方面表现出高度活跃的性质。
A practical, three-step synthetic route to 9-azabicyclo[3.3.1] nonane N-oxyl (ABNO, 3), an unhindered, stable class of nitroxyl radical, has been developed. ABNO exhibits a highly active nature compared with TEMPO in the catalytic oxidation of alcohols to their corresponding carbonyl compounds.