Synthesis of [60]fullerene adducts bearing carbazole moieties by Bingel reaction and their properties.
Synthesis of [60]fullerene adducts bearing carbazole moieties by Bingel reaction and their properties.
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DOI：
10.1021/ol048952n
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发表时间：
2004-07
期刊：
影响因子：
5.2
通讯作者：
Yosuke Nakamura;Masato Suzuki;Y. Imai;J. Nishimura*
中科院分区：
文献类型：
--
作者：
Yosuke Nakamura;Masato Suzuki;Y. Imai;J. Nishimura*
利用带有一个或两个丙二酸乙酯的咔唑衍生物，通过Bingel反应成功地制备了咔唑连接的[60]富勒烯加合物。在后一种情况下，获得特定的双加成物区域异构体，这取决于两个丙二酸乙酯部分之间的间隔单元。[反应：见正文]
Carbazole-linked [60]fullerene adducts were successfully prepared by the Bingel reactions using carbazole derivatives bearing one or two ethyl malonate moieties. In the latter cases, specific bisadduct regioisomers were obtained, depending on the spacer unit between two ethyl malonate moieties. [reaction: see text]