Stable isotope composition of bentonites from the Swiss and Bavarian Freshwater Molasse as a proxy for paleoprecipitation

Stable isotope composition of bentonites from the Swiss and Bavarian Freshwater Molasse as a proxy for paleoprecipitation
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来自瑞士和巴伐利亚淡水磨拉石的膨润土的稳定同位素组成作为古降水的代表

DOI:
10.1016/j.palaeo.2016.02.002
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发表时间:
2016
期刊:
Palaeogeography, Palaeoclimatology, Palaeoecology
影响因子:
--
通讯作者:
Vennemann
Vennemann
中科院分区:
--
文献类型:
--
作者:
Vennemann

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测定了北阿尔卑斯山前陆盆地膨润土和富蒙脱石凝灰岩的氢、氧同位素组成,年龄为9~21 Ma。假设在火山灰层沉积后不久形成粘土矿物,并根据古气候研究估计的地表温度,可以计算出与粘土矿物平衡的水的H和O同位素组成。与莫拉塞盆地其他古沉淀物(如土壤碳酸盐和哺乳动物遗骸)以及膨润土层中碳酸盐的δ18O值的对比表明,用该方法估算的水的δ18O值对于此时和该地区的前陆降水是典型的。因此,膨润土和蚀变凝灰岩中蒙脱石的δ~(18)O值可作为古气候和古地形研究的有用工具。然而,有迹象表明,粘土矿物没有保留其最初的氢同位素组成,但发生了氢同位素的形成后交换。
The hydrogen and oxygen isotope compositions of bentonites and smectite-rich tuffs from the North Alpine Foreland Basin were measured for samples dated between 9 and 21 Ma. Assuming clay mineral formation shortly after the deposition of the volcanic ash layers and at surface temperatures estimated from paleoclimatic studies, the H and O isotope composition of water in equilibrium with the clay minerals can be calculated. A comparison with values derived from other proxies of paleoprecipitation in the Molasse Basin (such as pedogenic carbonates and mammal remains) andδ18O values of carbonate in the bentonite beds, suggests that theδ18O values of water estimated by this method are typical for foreland precipitation at this time and for this region. Therefore, theδ18O value of smectite in bentonites and altered tuff layers can be a useful tool for studies of paleoclimate and -topography. There are, however, indications that the clay minerals did not retain their initial hydrogen isotopic composition, but that a postformational exchange of H isotopes has occurred.
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