Two phases of [Me4N][Ni(dmise)2]2: syntheses, crystal structures, electrical conductivities, and intermolecular orbital overlap calculations of .alpha.- and .beta.-tetramethylammonium bis[bis(2-selenoxo-1,3-dithiole-4,5-dithiolato)nickelate], the first conductors based on the M(C3S4Se)2 system
Two phases of [Me4N][Ni(dmise)2]2: syntheses, crystal structures, electrical conductivities, and intermolecular orbital overlap calculations of .alpha.- and .beta.-tetramethylammonium bis[bis(2-selenoxo-1,3-dithiole-4,5-dithiolato)nickelate], the first conductors based on the M(C3S4Se)2 system
复制标题
[Me4N][Ni(dmise)2]2 的两相：α-和β-四甲基铵双[bis(2-selenoxo-1,3)的合成、晶体结构、电导率和分子间轨道重叠计算
DOI：
10.1021/ic00069a029
复制
发表时间：
1993
影响因子：
4.6
通讯作者：
J. Reedijk
中科院分区：
文献类型：
--
作者：
J. P. Cornelissen;B. Pomarède;A. Spek;D. Reefman;J. Haasnoot;J. Reedijk
溶液[Me 4 N][Ni(dmise) 2 ] (dmise=C 3 S 4 Se 2- =2-selenoxo-1,3-dithiole-4,5-dithiolate)的电化学氧化产生α-[Me 4 N][Ni(dmise) 2 ] 2 (I)的片状晶体。在大量过量的 Me 4 NPF 6 存在下，[Bu 4 N][Ni(dmise) 2 ] 2 电氧化生成 α-[Me 4 N][Ni(dmise) 2 ] 2 和 β-[Me 4 N][Ni(dmise) 2 ] 2 (II) 针状晶体。对两种化合物进行了单晶 X 射线测量
Electrochemical oxidation of a solution [Me 4 N][Ni(dmise) 2 ] (dmise=C 3 S 4 Se 2- =2-selenoxo-1,3-dithiole-4,5-dithiolate) yields platelet-shaped crystals of α-[Me 4 N][Ni(dmise) 2 ] 2 (I). Electrooxidation of [Bu 4 N][Ni(dmise) 2 ] 2 in the presence of a large excess of Me 4 NPF 6 yields both α-[Me 4 N][Ni(dmise) 2 ] 2 and needle-shaped crystals of β-[Me 4 N][Ni(dmise) 2 ] 2 (II). Single-crystal X-ray measurements were carried out for both compounds