Can the second virial coefficient be a predictor for the critical temperature?
Can the second virial coefficient be a predictor for the critical temperature?
复制标题
第二维里系数可以预测临界温度吗？
DOI：
10.1080/08927020701459688
复制
发表时间：
2007-12
影响因子：
2.1
通讯作者：
Zhou, S
中科院分区：
文献类型：
--
作者：
Zhou, S
A recently proposed 3rd-order thermodynamic perturbation theory (TPT) is employed to calculate critical parameters of several model fluids. It is found that no matter how dis-continuous or continuous attractive perturbation part of whole interaction potential is, the 3rd-order TPT is accurate reliably for prediction of the critical parameters only on condition that the interaction potential is long-ranged or intermediate-ranged. Even when the 2nd-order macroscopic compressibility approximation TPT (2nd-order MCA-TPT) completely fails, the 3rd-order TPT still performs well. The 3rd-order TPT is then used to investiagte in detail validity and range of a recently emerging empirical rule. It is found that the empirical rule only applies for potentials consisting of a hard sphere core and a continuous and attractive perturbation tail, whether the attractive perturbation tail is differentiable with respect to particle separation or not does not matter. But for potentials with dis-continuous perturbation tail and those diaplaying two fluid–fluid critical points, the empirical rule fails completely.
登录
查看更多内容
影响因子：
1.7
作者：
Lj. Milanović;H. Posch;W. Hoover
通讯作者：
Lj. Milanović;H. Posch;W. Hoover
影响因子：
4.4
作者：
G. Vliegenthart;H. Lekkerkerker
通讯作者：
G. Vliegenthart;H. Lekkerkerker
影响因子：
4.4
作者：
L. Mederos;G. Navascués
通讯作者：
L. Mederos;G. Navascués
影响因子：
1.7
作者：
D. Pini;A. Parola;L. Reatto
通讯作者：
D. Pini;A. Parola;L. Reatto
DOI：
10.1002/cphc.200600516
发表时间：
2007-01
期刊：
Chemphyschem : a European journal of chemical physics and physical chemistry
影响因子：
--
作者：
Shiqi Zhou;A. Jamnik;Elie Wolfe;S. Buldyrev
通讯作者：
Shiqi Zhou;A. Jamnik;Elie Wolfe;S. Buldyrev