Carbon monoxide chemisorption on Ni(100)—direct detection of adsorbate-adsorbate interactions by desorption kinetic measurements
Carbon monoxide chemisorption on Ni(100)—direct detection of adsorbate-adsorbate interactions by desorption kinetic measurements
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Ni(100) 上的一氧化碳化学吸附——通过解吸动力学测量直接检测吸附质-吸附质相互作用
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发表时间：
1980
期刊：
影响因子：
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通讯作者：
D. Goodman
中科院分区：
文献类型：
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作者：
J. Yates;D. Goodman
用热脱附谱研究了CO在Ni（100）表面上的化学吸附与CO（g）之间的同位素交换。快速同位素交换发生在低晶体温度，并推测涉及低吸附能的CO状态，这是目前在高CO覆盖率的Ni（100）。交换伴随着交换的CO在整个CO层中的快速平衡。
The isotopic exchange between CO chemisorbed on Ni(100) and CO(g) has been studied using thermal desorption spectroscopy. Rapid isotopic exchange occurs at low crystal temperatures, and presumably involves low adsorption energy CO states which are present at high CO coverages on the Ni(100). Exchange is accompanied by rapid equilibration of exchanged CO throughout the entire CO layer.