Self-Assembly of Amphiphilic Homopolymers Bearing Ferrocene and Carboxyl Functionalities: Effect of Polymer Concentration, β-Cyclodextrin, and Length of Alkyl Linker
Self-Assembly of Amphiphilic Homopolymers Bearing Ferrocene and Carboxyl Functionalities: Effect of Polymer Concentration, β-Cyclodextrin, and Length of Alkyl Linker
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DOI：
10.1021/la402335d
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发表时间：
2013-08-27
期刊：
影响因子：
3.9
通讯作者：
Huang, Xiaoyu
中科院分区：
文献类型：
--
作者：
Feng, Chun;Lu, Guolin;Huang, Xiaoyu
首先在温和的条件下通过多步亲核取代反应和可逆加成断裂链转移(RAFT)均聚反应合成了三种新的含有二茂铁和叔丁酯基团的丙烯酰胺单体，得到了分子量分布较窄的均聚物(M-w/M-n
Three new acrylamide monomers containing ferrocene and tert-butyl ester groups were first synthesized via multistep nucleophilic substitution reaction under mild conditions followed by reversible addition fragmentation chain transfer (RAFT) homopolymerization to give well-defined homopolymers with narrow molecular weight distributions (M-w/M-n