Experiment of Recovery of Tritium from Li by Y and Design of Hot Trap

Experiment of Recovery of Tritium from Li by Y and Design of Hot Trap
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Y法从锂中回收氚的实验及热阱设计

DOI:
10.13182/fst08-a1777
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发表时间:
2008
影响因子:
0.9
通讯作者:
Yuuki Edao
Yuuki Edao
中科院分区:
工程技术4区
文献类型:
--
作者:
S. Fukada;Yasushi Maeda;Yuuki Edao

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摘要:研究了Y板从中子辐照Li中回收氚T的实验研究,设计了Y热阱从流动的IFMIF Li靶环中去除氚T。在300-500°的Y板上成功地除去了Li在0.01 ~ 0.05ppm的摩尔分数中产生的T。还原T与生成T之比随温度和浸泡时间的增加而增加。Li释放的T以HT为主,不吸收Y的以HTO为主。SEM-EDX分析表明,Li中不仅有T的转移,还有作为杂质的O的转移。用HF处理Y能有效去除接收Y板上形成的氧化物,提高Y板的加氢速率。本文给出了设计用于IFMIF流动Li靶回路的Y型热阱的条件。
Abstract The recovery of tritium, T, from neutron-irradiated Li by a Y plate was experimentally investigated, and a Y hot trap was designed to remove T from a flowing Li target loop of IFMIF. T generated in Li ranging from 0.01 to 0.05ppm in molar fraction was successfully removed by a Y plate at 300-500°. The ratio of recovered T to generated one increased with temperature and immersion time. HT was the main chemical species of T that was released from Li, while HTO was the main one without Y absorption. SEM-EDX analysis revealed the transfer of not only T but also O originally included in Li as an impurity. Treatment of Y by HF was effective to remove oxides formed on the as-received Y plate and enhanced its hydrogenating rate. Conditions of a Y hot trap designed for the flowing Li target loop of IFMIF are given in the present paper.
DOI: --
发表时间: 2007
期刊: Fusion Engineering and Design 82
影响因子: --
作者:
S.Fukada;M.Kinoshita;Y.Maeda;T.Muroga
通讯作者: T.Muroga