Supramolecular Differentiation for Construction of Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth.
Supramolecular Differentiation for Construction of Anisotropic Fullerene Nanostructures by Time-Programmed Control of Interfacial Growth.
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DOI：
10.1021/acsnano.6b04535
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发表时间：
2016-08
期刊：
影响因子：
17.1
通讯作者：
P. Bairi;K. Minami;Jonathan P. Hill;Waka Nakanishi;L. Shrestha;Chao Liu;Koji Harano;E. Nakamura;K. Ariga
中科院分区：
文献类型：
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作者：
P. Bairi;K. Minami;Jonathan P. Hill;Waka Nakanishi;L. Shrestha;Chao Liu;Koji Harano;E. Nakamura;K. Ariga
超分子组装可以通过利用多种非共价相互作用的累积效应来构建各种各样的有序结构。然而，各向异性纳米结构的构造仍然受到一些限制。在这里，我们展示了制备各向异性富勒烯基纳米结构的超分子分化，这是多个组装策略的程序控制。我们仔细结合界面组装和局部相分离现象。两个富勒烯衍生物，PhH和C12 H，一起形成自组装各向异性纳米结构，通过使用这种方法。该技术适用于各向异性纳米结构的构建，而不需要复杂的分子设计或复杂的方法。
Supramolecular assembly can be used to construct a wide variety of ordered structures by exploiting the cumulative effects of multiple noncovalent interactions. However, the construction of anisotropic nanostructures remains subject to some limitations. Here, we demonstrate the preparation of anisotropic fullerene-based nanostructures by supramolecular differentiation, which is the programmed control of multiple assembly strategies. We have carefully combined interfacial assembly and local phase separation phenomena. Two fullerene derivatives, PhH and C12H, were together formed into self-assembled anisotropic nanostructures by using this approach. This technique is applicable for the construction of anisotropic nanostructures without requiring complex molecular design or complicated methodology.