Photoelectron spectroscopy of S1 toluene: II. Intramolecular dynamics of selected vibrational levels in S1 toluene studied by nanosecond and picosecond time-resolved photoelectron spectroscopies.
Photoelectron spectroscopy of S1 toluene: II. Intramolecular dynamics of selected vibrational levels in S1 toluene studied by nanosecond and picosecond time-resolved photoelectron spectroscopies.
复制标题
S1甲苯的光电子能谱：II。
DOI：
10.1063/1.2126974
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发表时间：
2005
期刊：
影响因子：
--
通讯作者：
P. Matousek
中科院分区：
文献类型：
--
作者：
Paul T. Whiteside;A. King;J. Davies;K. L. Reid;M. Towrie;P. Matousek
我们的结果表明，S(1)甲苯的光物理比相关分子对氟甲苯或对二氟苯的光物理要复杂得多。我们在不同的时间尺度和不同的温度下测量了一些S(1)内能的光电子能谱范围，试图解开竞争过程，但最终结论仍然很突出。
We present results which suggest that the photophysics of S(1) toluene is significantly more complicated than that of the related molecules p-fluorotoluene or p-difluorobenzene. We have measured a range of photoelectron spectra for a number of S(1) internal energies, on different time scales and at different temperatures, in an attempt to unravel the competing processes, but the final conclusion remains outstanding.