SIMULTANEOUS DETERMINATION OF NATURAL AND STYRENE BUTADIENE RUBBER TIRE TREAD PARTICLES IN ATMOSPHERIC DUSTS BY PYROLYSIS-GAS CHROMATOGRAPHY

SIMULTANEOUS DETERMINATION OF NATURAL AND STYRENE BUTADIENE RUBBER TIRE TREAD PARTICLES IN ATMOSPHERIC DUSTS BY PYROLYSIS-GAS CHROMATOGRAPHY
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DOI:
10.1016/0165-2370(89)80035-x
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发表时间:
1989-05-01
影响因子:
6
通讯作者:
WHANG, KJ
WHANG, KJ
中科院分区:
化学2区
文献类型:
--
作者:
LEE, YK;KIM, MG;WHANG, KJ

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介绍了一种同时测定大气粉尘中天然橡胶(NR)和丁苯橡胶(SBR)胎面胶颗粒的方法。颗粒橡胶在740 ℃热解。在居里点热解器中加热5秒钟。用配备双火焰离子化检测器的气相色谱仪分离和检测所得热解物。在几种裂解产物中,异戊二烯和苯乙烯分别被选为NR和SBR的指示化合物。该方法适用于一套大气粉尘样品收集在首尔,韩国的安德森采样器和一些分析结果。
A method for simultaneous determination of natural rubber (NR) and styrene-butadiene rubber (SBR) tire tread particles in atmospheric dust is described. Particulate rubbers are pyrolyzed at 740.degree. C for five seconds in a Curie-point pyrolyzer. The resulting pyrolyzates are separated and detected by a gas chromatograph equipped with dual flame ionization detectors. Among several pyrolysis products, isoprene and styrene are chosen as indicator compounds for NR and SBR, respectively. The method is applied to a suite of atmospheric dust samples collected in Seoul, Korea by an Andersen sampler and some analytical results are presented.