A directly grown pristine Cu-CAT metal-organic framework as an anode material for high-energy sodium-ion capacitors
A directly grown pristine Cu-CAT metal-organic framework as an anode material for high-energy sodium-ion capacitors
复制标题
直接生长的原始 Cu-CAT 金属有机骨架作为高能钠离子电容器的阳极材料
DOI：
10.1039/c9cc06048k
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发表时间：
2019
影响因子：
4.9
通讯作者：
Liu Jinping
中科院分区：
文献类型：
--
作者：
Zhou Wan;Lv Si;Liu Xiaolin;Li Yuanyuan;Liu Jinping
首次直接生长了铜基金属有机骨架（Cu-CAT）纳米线作为钠离子混合电容器（SIHC）的阳极。均匀的分子孔为Na+的扩散提供了一个自然的通道，并为Na+与C-O活性中心的配位提供了充足的空间，这两个因素分别极大地促进了与电容阴极的动力学平衡和提高了SIHC的能量密度。
Copper-based metal–organic framework (Cu-CAT) nanowires are directly grown as an anode of sodium ion hybrid capacitors (SIHCs) for the first time. The uniform molecular pores provide a natural Na+ diffusion pathway and abundant accommodations for Na+ coordination to the C–O active sites, which greatly facilitate the kinetics balance with the capacitive cathode and boost the energy density of SIHCs, respectively.