Separating the vibrationally resolved Auger decay channels for a CO core hole state.
Separating the vibrationally resolved Auger decay channels for a CO core hole state.
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DOI:
10.1103/physrevlett.100.143003
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发表时间:
2008-04
影响因子:
8.6
通讯作者:
V. Ulrich;S. Barth;S. Joshi;T. Lischke;A. Bradshaw;U. Hergenhahn
中科院分区:
文献类型:
--
作者:
V. Ulrich;S. Barth;S. Joshi;T. Lischke;A. Bradshaw;U. Hergenhahn
The K-VV Auger spectrum of carbon monoxide (CO) excited by C 1s photoionization has been investigated with a novel electron-electron coincidence setup. The energy resolution is sufficiently high to resolve the vibrational energy levels of the core-ionized intermediate state and of most dicationic final states in the two-dimensional electron energy map. We demonstrate how the influence of vibrational states on a molecular Auger spectrum can be accessed experimentally without the constraint of averaging over all intermediate state energies.