High proton conductivity of one-dimensional ferrous oxalate dihydrate.
High proton conductivity of one-dimensional ferrous oxalate dihydrate.
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DOI：
10.1021/ja808681m
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发表时间：
2009-02
影响因子：
15
通讯作者：
Teppei Yamada;Masaaki Sadakiyo;H. Kitagawa
中科院分区：
文献类型：
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作者：
Teppei Yamada;Masaaki Sadakiyo;H. Kitagawa
质子传导材料由于其对燃料电池或传感器的电解质的效用而变得重要。一维配位聚合物，草酸亚铁二水合物的质子电导率进行了评估，发现在环境温度下显示1.3 mS cm（-1）。该化合物在室温下具有极高的质子导电性，且不含任何强酸基团，这一结果暗示了由配位聚合物组成的新型质子导电材料。
Proton conductive materials become important for their utility to electrolytes of fuel cells or sensors. The proton conductivity of a one-dimensional coordination polymer, ferrous oxalate dihydrate, was evaluated and found to show 1.3 mS cm(-1) at ambient temperature. The proton conductivity of this compound is extremely high at ambient temperature without any strong acidic group, and this result is suggestive of new proton conductive materials consisting of coordination polymers.