Sequential, Kinetically Controlled Synthesis of Multicomponent Stereoisomeric Assemblies

Sequential, Kinetically Controlled Synthesis of Multicomponent Stereoisomeric Assemblies
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DOI:
10.1002/anie.201108994
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发表时间:
2012-01-01
影响因子:
16.6
通讯作者:
Lusby, Paul J.
Lusby, Paul J.
中科院分区:
化学1区
文献类型:
--
作者:
Chepelin, Oleg;Ujma, Jakub;Lusby, Paul J.

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顺式可交换铂配位的不稳定性的巨大差异已被利用来利用无模板、顺序、动力学控制的方法选择性地合成多组分立体异构体组件。
The vast difference in labilities of cis-exchangeable platinum coordination sites has been exploited to selectively synthesise multicomponent stereoisomeric assemblies using a template-free, sequential, kinetically controlled approach.