Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic-Templated Holmium Sulfate with 1D Single Ladder Chains.
Solvothermal Synthesis, Crystal Structure, and Properties of a New Organic-Templated Holmium Sulfate with 1D Single Ladder Chains.
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DOI：
10.1002/chin.201023014
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发表时间：
2010-04
期刊：
影响因子：
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通讯作者：
Wanli Zhou;Xiaorun Ding;Zhibin Zhang;Leizhi Zheng;Yan Xu;Dunru Zhu
中科院分区：
文献类型：
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作者：
Wanli Zhou;Xiaorun Ding;Zhibin Zhang;Leizhi Zheng;Yan Xu;Dunru Zhu
合成了一种新的有机胺模板一维硫酸钬[Ho（SO4）2·H2O]（1），并通过X射线单晶衍射、红外光谱、热重分析、X射线衍射和扫描电子显微镜对其结构进行了表征。骨架1的结构由HoO 8多面体和SO 4四面体构成。S（1）和S（2）通过三个S-O-Ho键将Ho（1）和它的晶体学伙伴连接成双链，而相邻的双链通过μ 3-O（O5）原子连接成一种新的单梯链。
A new organic amine templated 1D holmium sulfate (C2H8N)[Ho(SO4)2·H2O] (1) has been synthesized and solvothermally and structurally characterized by single-crystal X-ray diffraction, IR spectroscopy, thermogravimetric and X-ray diffraction analyses as well as scanning electron microscopy (SEM). The structure of framework 1 is constructed from HoO8 polyhedra and SO4 tetrahedra. S(1) and S(2) connects Ho(1) and its crystallographic partners by using three S–O–Ho linkages to generate double chains, whereas the adjacent double chain are connected by μ3-O (O5) atoms to form a novel single ladder chains.