Sulfur-Bridged Dinuclear and Tetranuclear Complexes Consisting of cis-[Ru(bpy)2]2+ and cis-[Ni(aet)2] Units
Sulfur-Bridged Dinuclear and Tetranuclear Complexes Consisting of cis-[Ru(bpy)2]2+ and cis-[Ni(aet)2] Units
复制标题
由 cis-[Ru(bpy)2]2 和 cis-[Ni(aet)2] 单元组成的硫桥双核和四核配合物
DOI：
10.1246/bcsj.79.1745
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发表时间：
2006
影响因子：
4
通讯作者：
T. Konno
中科院分区：
文献类型：
--
作者：
T. Yoshimura;A. Shinohara;M. Hirotsu;K. Ueno;T. Konno
[Ru（bpy）2（solvent）2]2+（bpy = 2，2 '-bipyridine）与[Ni（aet）2]（aet = 2-aminoethanethiolate）1：1反应，得到S-桥连的八元Ru 2Ni 2S 4金属配合物[{Ru（bpy）2 } 2 -{Ni（aet）2 } 2 ] 4+，而[Ru（bpy）2（solvent）2]2+与[Ni（aet）2] 1：2反应，得到S-桥连的四元RuNiS 2金属配合物[Ru（bpy）2 -{Ni（aet）2 }] 2 +.
The 1:1 reaction of [Ru(bpy)2(solvent)2]2+ (bpy = 2,2'-bipyridine) with [Ni(aet)2] (aet = 2-aminoethanethiolate) gave a S-bridged Ru II 2 Ni II 2 tetranuclear complex with an eight-membered Ru 2 Ni 2 S 4 metallacycle, [{Ru(bpy) 2 } 2 -{Ni(aet) 2 } 2 ] 4+ , while a S-bridged Ru II Ni II dinuclear complex with a four-membered RuNiS2 metallacycle, [Ru(bpy) 2 -{Ni(aet) 2 }] 2+ , was obtained by the corresponding 1:2 reaction between [Ru(bpy)2(solvent)2]2+ and [Ni(aet)2].