Photofragmentation of symmetric triatomic molecules: Time dependent picture
Photofragmentation of symmetric triatomic molecules: Time dependent picture
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对称三原子分子的光断裂：时间依赖性图片
DOI：
10.1063/1.436197
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发表时间：
1978
影响因子：
4.4
通讯作者：
E. Heller
中科院分区：
文献类型：
--
作者：
E. Heller
利用最近的全光解截面的时间依赖公式，对对称三原子（XY2）真空紫外光谱的线形和吸收包络进行了定性解释。注意到截面对潜在表面参数和初始振动波函数性质的依赖。这里处理的对称三原子情况说明了可以应用于更复杂的非对称多原子情况的技术。
A recent time dependent formulation of total photodissociation cross sections is exploited to give a qualitative explanation of line shapes and absorption envelopes for symmetric triatomic (XY2) vacuum uv spectra. Attention is given to the dependence of the cross section on potential surface parameters and on the nature of the initial vibrational wavefunctions. The symmetric triatomic case treated here is illustrative of techniques which can be applied to more complicated, unsymmetric polyatomic situations.