A thermogravimetric study of nonfossil solid fuels. 1. Inert pyrolysis
A thermogravimetric study of nonfossil solid fuels. 1. Inert pyrolysis
复制标题
DOI：
10.1021/ef0102059
复制
发表时间：
2002-05-01
期刊：
影响因子：
5.3
通讯作者：
Salatino, P
中科院分区：
文献类型：
--
作者：
Senneca, O;Chirone, R;Salatino, P
用非等温热重法研究了六种非常规燃料从低升温速率(5℃/min)到高升温速率(高达900℃/min)的热解过程。测试的燃料包括塑料、橡胶和木质纤维材料，即聚乙烯、聚对苯二甲酸乙二酯、废轮胎、硬质橡胶、新鲜生物质和废木。给出了每种材料的热解动力学表达式。讨论了热降解机理，以强调材料之间的差异和相似之处。
Pyrolysis of six nonconventional fuels has been studied by means of nonisothermal thermogravimetric analysis from low (5 degreesC/min) to high heating rates (as large as 900 degreesC/min). The fuels tested included plastics, rubbers, and ligno-cellulosic materials, namely, polyethylene, poly-(ethylene terephthalate), scrap tires, ebonite, a fresh biomass, and waste wood. A kinetic expression for pyrolysis is provided for each material. The mechanisms of thermal degradation are discussed in order to underline differences and similarities between materials.