Regioselective electrophilic borylation of haloarenes
Regioselective electrophilic borylation of haloarenes
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DOI：
10.1039/c4cc10153g
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发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
Ingleson, Michael J.
中科院分区：
文献类型：
--
作者：
Del Grosso, Alessandro;Carrillo, Josue Ayuso;Ingleson, Michael J.
卤代芳烃用胺：BCl3:AlCl3按1:1:2的比例直接硼化。酯化反应后，产率高，区域选择性受空间和电子效应控制。
Haloarenes undergo direct borylation using amine : BCl3:AlCl3 in the ratio of 1 : 1 : 2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.