Anion recognition through hydrogen bonding: a simple, yet highly sensitive, luminescent metal-complex receptor
Anion recognition through hydrogen bonding: a simple, yet highly sensitive, luminescent metal-complex receptor
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DOI：
10.1039/b004541l
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发表时间：
2000
影响因子：
4.9
通讯作者：
Shih‐Sheng Sun;A. J. Lees
中科院分区：
文献类型：
--
作者：
Shih‐Sheng Sun;A. J. Lees
设计并合成了一种新的基于多吡啶基的发光受体，用于多种无机阴离子，这种人工受体对卤化物，氰化物和乙酸根阴离子表现出高亲和力，结合常数高达104-105 M−1，在CH 2Cl 2溶液中的检测限低至10−8 M。
A new luminescent rhenium(I) polypyridyl-based receptor for a variety of inorganic anions has been designed and synthesized and this artificial receptor shows high affinities for halides, cyanide and acetate anions with binding constants as high as 104–105 M−1 and a detection limit as low as 10−8 M in CH2Cl2 solution.