Preorganized Frustrated Lewis Pairs
Preorganized Frustrated Lewis Pairs
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DOI：
10.1021/ja210214r
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发表时间：
2012-01-11
影响因子：
15
通讯作者：
Lammertsma, Koop
中科院分区：
文献类型：
--
作者：
Bertini, Federica;Lyaskoyskyy, Volodymyr;Lammertsma, Koop
当供体和受体位置完全对齐时，双子星受挫刘易斯对（FLPs）的反应性有望增强。非氟化FLP tBu(2)PCH(2)BPh(2)与H-2、CO2和异氰酸酯的反应表明了这一点，并支持了计算。
Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu(2)PCH(2)BPh(2) with H-2, CO2, and isocyanates and supported computationally.