Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes
Redox-regulated divergence in photocatalytic addition of α-nitro alkyl radicals to styrenes
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DOI：
10.1039/d0cc04821f
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发表时间：
2020-09-25
影响因子：
4.9
通讯作者：
Ooi, Takashi
中科院分区：
文献类型：
--
作者：
Tsuchiya, Yuto;Onai, Ryota;Ooi, Takashi
建立了α-溴硝基烷与苯乙烯衍生物反应的发散光催化体系，其中作为连接中间体的持久性硝酰基自由基的产生和适当调节体系的氧化还原能力构成了对可能的反应途径实现严格控制的关键要素。
A divergent photocatalytic system for the reaction of alpha-bromo nitroalkanes with styrene derivatives is established, wherein the generation of the persistent nitroxyl radical as a junctional intermediate and suitable tuning of the redox ability of the system constitute the crucial elements for achieving rigorous control over the possible reaction pathways.