Synthesis of soluble poly(9,10-dihydrophenanthrene-2,7-diyl)s. A new class of luminescent poly(p-phenylene)s with ethylene type bridges
Synthesis of soluble poly(9,10-dihydrophenanthrene-2,7-diyl)s. A new class of luminescent poly(p-phenylene)s with ethylene type bridges
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可溶性聚(9,10-二氢菲-2,7-二基)的合成。
DOI：
10.1016/j.polymer.2004.09.060
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发表时间：
2004
期刊：
影响因子：
4.6
通讯作者：
Hiroki Fukumoto
中科院分区：
文献类型：
--
作者：
Takakazu Yamamoto;Takahiro Asao;Hiroki Fukumoto
通过使用零价镍配合物对相应单体进行脱卤缩聚，合成了在 9,10 位上带有 –OSi(R)2(R') 基团的聚（9,10-二氢菲-2,7-二基）。它们显示出 9800-69,000 的数均分子量 (Mn) 和光致发光的高量子产率（62% 定量）。钯催化 9,10 位具有 –OCH3 或 –OSi(R)2(R') 基团的 2,7-二溴-9,10-二氢菲与二乙炔基或二硼芳香族化合物的共聚也产生了具有高量子产率的光致发光聚合物。
Poly(9,10-dihydrophenanthrene-2,7-diyl)s with –OSi(R)2(R′) groups at the 9,10-positions were synthesized by dehalogenative polycondensation of the corresponding monomers by using a zerovalent nickel complex. They showed number average molecular weights (Mn's) of 9800–69,000 and high quantum yields (62%-quantitative) in photoluminescence. Palladium catalyzed copolymerization of 2,7-dibromo-9,10-dihydrophenanthrene having –OCH3or –OSi(R)2(R′) groups at the 9,10-positions with diethynyl- or diboronic-aromatic compounds also gave photoluminescent polymers with high quantum yields.