The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum
The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum
复制标题
DOI：
10.1063/1.1699045
复制
发表时间：
1953-05
影响因子：
4.4
通讯作者：
R. Trambarulo;S. Ghosh;C. Burrus;W. Gordy
中科院分区：
文献类型：
--
作者：
R. Trambarulo;S. Ghosh;C. Burrus;W. Gordy
在42至118 kmc的区域中测量到0316的四个低J旋转跃迁。测得的转动光谱常数为A = 106，530.0 ±1.1 Mc，B = 13，349.06 ±0.06 Mc，C = 11，834.3 ±1.1 Mc。氧核呈等腰三角形，顶角为116°49′±30′，两个相等的核间距为1.278±0.003A。从20，2 → 11，1跃迁的斯塔克分裂得到偶极矩为0.53±0.02德拜。塞曼分裂的这种过渡表明，臭氧是没有显着的顺磁性。
Four low‐J rotational transitions of 0316 have been measured in the region from 42 to 118 kmc. The rotational spectroscopic constants found are A = 106,530.0±1.1 Mc, B = 13,349.06±0.06 Mc, C = 11,834.3±1.1 Mc. The oxygen nuclei form an isosceles triangle with an apex angle of 116°49′±30′, and the two equal internuclear distances are 1.278±0.003A. From the Stark splitting of the 20,2→11,1 transition the dipole moment is 0.53±0.02 debye. Zeeman splittings of this transition show that ozone is not significantly paramagnetic.