Metal-Organic Frameworks and Their Composites: Synthesis and Electrochemical Applications
Metal-Organic Frameworks and Their Composites: Synthesis and Electrochemical Applications
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金属有机骨架及其复合材料：合成和电化学应用
DOI：
10.1002/smtd.201700187
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发表时间：
2017
期刊：
影响因子：
12.4
通讯作者：
Xu Qiang
中科院分区：
文献类型：
--
作者：
Yi Fei Yan;Zhang Rui;Wang Hailong;Chen Li Feng;Han Lei;Jiang Hai Long;Xu Qiang
金属有机骨架（mof）是一种年轻的晶体多孔材料，由无机顶点（金属离子或簇）和有机配体组装而成，具有超高孔隙率、高表面积、合成和结构可定制性以及相对容易合成的特点，是大量应用的优秀候选者。近年来，人们对环境和能源电化学领域的研究兴趣日益浓厚。人们设计、制备了大量的MOFs，并将其应用于电化学领域。本文对电化学定向功能MOF和MOF复合材料的合理制备进行了评价。总结了增强相应MOF电化学行为的综合策略，并讨论了结构与电化学性能的关系。本文的研究成果将为今后开发具有优异电化学性能的MOF及其复合材料提供参考。
As a youthful family of crystalline porous materials, metal–organic frameworks (MOFs), assembled by inorganic vertices (metal ions or clusters) and organic ligands, feature ultrahigh porosity, high surface area, and synthetic and structural tailorability, along with relatively easy synthesis, making them excellent candidates for a large number of applications. Recently, increasing research interest in the electrochemical fields with regard to the environment and energy has been received. Lots of MOFs have been designed, prepared, and used in electrochemical applications, exhibiting fascinating performances. Here, the rational fabrication of electrochemical‐application‐directed functional MOFs and MOF composites is appraised. The synthetic strategies for the enhancement of corresponding MOF electrochemical behaviors are summarized and the relationship between structure and electrochemical performance is discussed. It is expected that the summary will be helpful for the future development of related MOFs and MOF composites with an excellent electrochemical performance.