A Flexible Porous MOF Exhibiting Reversible Breathing Behavior through Single-Crystal to Single-Crystal Transformation
A Flexible Porous MOF Exhibiting Reversible Breathing Behavior through Single-Crystal to Single-Crystal Transformation
复制标题
柔性多孔 MOF 通过单晶到单晶的转变表现出可逆呼吸行为
DOI：
10.1002/slct.201601666
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发表时间：
2017
期刊：
影响因子：
2.1
通讯作者：
Hu Tong-Liang
中科院分区：
文献类型：
--
作者：
Wang Lin;He Wei-Wei;Yao Zhao-Quan;Hu Tong-Liang
采用混合配体策略合成了具有层内通道的二维（2D）柔性Zn(II) MOF(1)。有趣的是，在晶体状态下，1在溶解/溶解时表现出可逆的呼吸行为，引起响应性发光和可见颜色变化。此外，当暴露在潮湿的空气中或浸泡在各种有机溶剂中时，也会发生上述过程。
A two dimensional (2D) flexible Zn(II) MOF (1) with intra‐layer channels has been synthesized using a mixed ligand strategy. Interestingly, 1 exhibits reversible breathing behavior upon desolvation/resolvation in crystal state, causing responsive luminescence together with visible color changes. Furthermore, the above‐mentioned process even occurred when 1 exposed to humid atmosphere or immersed in various organic solvents.