A Green Method for the Selective Esterification of Primary Alcohols in the Presence of Secondary Alcohols or Aromatic Alcohols
A Green Method for the Selective Esterification of Primary Alcohols in the Presence of Secondary Alcohols or Aromatic Alcohols
复制标题
仲醇或芳香醇存在下伯醇选择性酯化的绿色方法
DOI：
10.1055/s-2001-15156
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发表时间：
2001
期刊：
影响因子：
2
通讯作者：
Hisashi Yamamoto
中科院分区：
文献类型：
--
作者：
K. Ishihara;Masayasu Nakayama;Suguru Ohara;Hisashi Yamamoto
Hf(IV)氯化物四氢呋喃配合物(1：2)，HfCl4·(THF)2是一种在仲醇或芳香醇存在下，伯醇与羧酸选择性酯化反应的高效催化剂。本方法作为一种环境和工业上理想的缩合方法特别有用。
: Hafnium(IV) chloride tetrahydrofuran complex (1:2), HfCl 4 • (THF) 2 , which is commercially available, is a highly effective catalyst for the selective esterification of primary alcohols with carboxylic acids in the presence of secondary alcohols or aromatic alcohols. The present method is especially useful as an environmentally and industrially ideal condensation.