THE TAMING OF CYCLOBUTADIENE
THE TAMING OF CYCLOBUTADIENE
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DOI：
10.1002/anie.199110241
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发表时间：
1991-08-01
期刊：
影响因子：
--
通讯作者：
THOMAS, R
中科院分区：
文献类型：
--
作者：
CRAM, DJ;TANNER, ME;THOMAS, R
环丁二烯的驯化是在血红素配体1的内部完成的。 环丁二烯是一种稳定的单重基态化合物，在1。 为了合成嵌段环丁二烯并对其结构进行表征，在1。 作者认为，把癌和癌的内相看作一种新的物态，是现实的，也是有益的。
The taming of cyclobutadiene was accomplished in the interior of the hemicarcerand 1. Cyclobutadiene is a stable compound with a singlet ground state when it is synthesized in the interior of 1. In order to synthesize the incarcerated cyclobutadiene and to characterize its structure, one bimolecular, three photochemical, and two thermal reactions were carried out in the interior of 1. The authors consider it both realistic and useful to regard the internal phase of carcerands and hemicarcerands as a new state of matter.