Inner-Sphere Heterogeneous Electrode Reactions. Electrocatalysis and Photocatalysis: The Challenge
Inner-Sphere Heterogeneous Electrode Reactions. Electrocatalysis and Photocatalysis: The Challenge
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DOI：
10.1021/ja101578m
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发表时间：
2010-06-09
影响因子：
15
通讯作者：
Bard, Allen J.
中科院分区：
文献类型：
--
作者：
Bard, Allen J.
本文提供了一个内球多相电子转移反应和电催化的观点，因为它是应用于电化学能量转换系统。基本概念和过去的方法来研究这些类型的反应的概述进行了讨论。简要描述了一种基于扫描电化学显微镜发现新的电催化剂（例如，用于氧还原反应的催化剂）和光催化剂（用于太阳能转化为燃料）的方法，以及用于量化中间体的新的表面询问技术。
This paper offers a perspective on inner-sphere heterogeneous electron-transfer reactions and electrocatalysis as it is applied to electrochemical energy conversion systems. Fundamental concepts and an overview of past approaches to studies of these types of reactions are discussed. A method for the discovery of new electrocatalysts (for example, ones for the oxygen reduction reaction) and photocatalysts (for solar energy conversion to fuels) based on scanning electrochemical microscopy is briefly described, as well as new surface interrogation techniques for quantifying intermediates.