A 2-alkyl substituted 2,3,1-benzodiazaborine.

A 2-alkyl substituted 2,3,1-benzodiazaborine.
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2-烷基取代的2,3,1-苯并二氮杂硼啉。

DOI:
10.1107/s0108270197012432
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发表时间:
1998
期刊:
Acta crystallographica. Section C, Crystal structure communications
影响因子:
--
通讯作者:
Chen,L
Chen,L
中科院分区:
--
文献类型:
--
作者:
Robinson,PD;Groziak,MP;Chen,L

文献摘要

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结构相关的2,3,1-benzodiheteroborines家族的第四个成员的结构已经通过晶体学手段解决,提供数据与其他人进行适当的直接比较。标题化合物1,2-二氢-1-羟基-2-甲基-2,3,1-苯并二氮杂硼杂环(C8 H9 BN 2 O)是由2-甲酰基苯硼酸和甲基肼缩合得到的,其内部几何构型和分子内缔合拓扑结构与其2-取代的母体化合物相似,但具有一些微妙的类似恶唑硼杂环的特征。
The structure of the fourth member of a family of structurally related 2,3,1-benzodiheteroborines has been solved by crystallographic means, providing data for proper direct comparison with the others. The title compound 1,2-dihydro-1-hydroxy-2-methyl-2,3,1-benzodiazaborine (C8H9BN2O) is obtained via condensation of 2-formylbenzeneboronic acid and methylhydrazine and is similar in most respects to its 2-unsubstituted parent, in internal geometry and intramolecular association topography, but has some subtle oxazaborine-like characteristics.