Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide.
Insertion reactions of a two-coordinate iron diaryl with dioxygen and carbon monoxide.
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DOI：
10.1039/b912312a
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发表时间：
2009-09
影响因子：
4.9
通讯作者：
Chengbao Ni;P. Power
中科院分区：
文献类型：
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作者：
Chengbao Ni;P. Power
铁(II)二芳基恐惧化合物‘2(1)(Ar’=C6H3-2，6-(C6H3-2，6-(I)Pr2)2)与O2或CO干净地反应生成单体双(芳氧基)Fe(Oar‘)2(2)或通过氧或CO插入Fe-C键得到eta2-酰基-羰基配合物(eta2-Ar’C=O)2Fe(CO)2(3)；配合物2具有严格的线性构型，表现出显著的抗O2氧化性能。
The iron(II) diaryl FeAr'2 (1) (Ar' = C6H3-2,6-(C6H3-2,6-(i)Pr2)2) reacts cleanly with O2 or CO to afford the monomeric, two-coordinate bis(aryloxide) Fe(OAr')2 (2) or the eta2-acyl-carbonyl complex (eta2-Ar'C=O)2Fe(CO)2 (3) via oxygen or CO insertion into the Fe-C bonds; complex 2 has a strictly linear geometry and shows remarkable resistance to O2 oxidation.