Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes
Palladium-catalyzed hydrophosphorylation and hydrophosphinylation of cyclopropenes
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DOI：
10.1021/ol8011138
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发表时间：
2008-08-07
期刊：
影响因子：
5.2
通讯作者：
Rubin, Michael
中科院分区：
文献类型：
--
作者：
Alnasleh, Bassam K.;Sherrill, William M.;Rubin, Michael
提出了一种新的过渡金属催化环丙烯双键加成P-H实体的方法。这种转化可以温和而有效地制备含磷环丙烷，收率高，非对映选择性高。
Novel transition-metal-catalyzed addition of P-H entities across the cyclopropene double bond has been developed. This transformation allows for mild and efficient preparation of phosphorus-containing cyclopropanes in good yields and high degrees of diastereoselectivity.