Rotational Spectrum of the Excited Vibrational States of DCOOH and Assignment of Optically Pumped Laser Transitions

Rotational Spectrum of the Excited Vibrational States of DCOOH and Assignment of Optically Pumped Laser Transitions
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DCOOH 激发振动态的旋转光谱和光泵浦激光跃迁的分配

DOI:
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发表时间:
1996
影响因子:
1.4
通讯作者:
Baskakov
Baskakov
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
Baskakov

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研究了DCOOH在175-335 GHz范围内的转动光谱。通过对光谱的分析,可以指定nu6、nu8和nu5振动态的几十个跃迁,并确定旋转和离心力的扭曲常数。导出的nu6态参数允许指定四个光泵浦的激光跃迁。此外,改进了DCOOH和D13COOH的基态参数,首次得到了DC18OOH和DCO18OH的基态参数。
The rotational spectrum of DCOOH in the 175-335 GHz region was investigated. Analysis of the spectrum made it possible to assign several dozen transitions in the nu6, nu8, and nu5 vibrational states and to determine the rotational and centrifugal distortion constants. The derived parameters of the nu6 state allowed four optically pumped laser transitions to be assigned. In addition, the ground state parameters for DCOOH and D13COOH have been improved and for the first time those for DC18OOH and DCO18OH have been obtained.