Synthesis of configurationally defined sexi- and octinaphthalene derivatives.
Synthesis of configurationally defined sexi- and octinaphthalene derivatives.
复制标题
构型确定的六萘和辛萘衍生物的合成。
作者：
K. Fuji*;T. Furuta;K. Tanaka
[图：使用光学活性的季萘与2-羟基萘酚部分的氧化偶联作为关键反应，合成了解释性定义的光学活性的八萘。通过与[6 + 2]偶合产物的比较，确定了其绝对构型。
[figure: see text] Configurationally defined optically active octinaphthalenes were synthesized using the oxidative coupling of optically active quaternaphthalenes with a 2-hydroxynaphthol moiety as a key reaction. The absolute configuration was determined by comparison with products of [6 + 2] coupling.