Electrochemically reduced graphene oxide modified acetylene black paste electrode for the sensitive determination of bisphenol A
Electrochemically reduced graphene oxide modified acetylene black paste electrode for the sensitive determination of bisphenol A
复制标题
电化学还原氧化石墨烯修饰乙炔黑糊电极用于灵敏测定双酚A
DOI：
10.1016/j.jelechem.2013.08.020
复制
发表时间：
2013-10-15
影响因子：
4.5
通讯作者：
Kuang, Yunfei
中科院分区：
文献类型：
--
作者：
Deng, Peihong;Xu, Zhifeng;Kuang, Yunfei
提出了一种基于石墨烯修饰乙炔黑糊电极（GR/ABPE）直接灵敏测定双酚A（BPA）的新方法。该修饰电极通过一步恒电位还原ABPE表面的剥离的氧化石墨烯片而获得。由于GR和AB的独特结构和优异性能，所制备的传感器对BPA的伏安响应比传统的碳糊电极有很大的提高。在优化条件下，BPA的线性范围为0.8 nM ~ 10.0 nM、10.0 nM ~ 8.0 μ M和8.0 μ M ~ 0.1 mM，检出限（SIN = 3）为0.6 nM。此外，这种新开发的方法具有一些明显的优点，包括极端简单，快速响应和低成本。GR/ABPE的实际分析性能通过评估塑料制品中BPA的检测与满意的回收率进行了检查。(C)2013爱思唯尔有限公司版权所有。
This paper has presented a novel strategy to carry out direct and sensitive determination of bisphenol A (BPA) based on the graphene modified acetylene black paste electrode (GR/ABPE). This modified electrode was obtained by one-step potentiostatic reduction of exfoliated graphene oxide sheets on the surface of ABPE. Due to the unique structure and extraordinary properties of GR and AB, the fabricated sensor displayed greatly improved voltammetric response to BPA compared with the conventional carbon paste electrode. Under the optimized conditions, the linear range for the detection of BPA was from 0.8 nM to 10.0 nM, 10.0 nM to 8.0 mu M and 8.0 mu M to 0.1 mM, with a detection limit (SIN = 3) of 0.6 nM. Additionally, this newly-developed method possesses some obvious advantages including extreme simplicity, rapid response and low cost. The practical analytical performance of the GR/ABPE was examined by evaluating the detection of BPA in plastic products with satisfied recovery. (C) 2013 Elsevier B.V. All rights reserved.