Unimolecular reactions at low energies and RRKM behavior: isomerization and dissociation
Unimolecular reactions at low energies and RRKM behavior: isomerization and dissociation
复制标题
低能单分子反应和 RRKM 行为：异构化和解离
DOI：
10.1021/j100237a008
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发表时间：
1983
期刊：
影响因子：
--
通讯作者：
A. Zewail
中科院分区：
文献类型：
--
作者：
L. R. Khundkar;R. Marcus;A. Zewail
电子激发反式二苯乙烯的异构化速率和异喹啉溶剂的解离速率
Rates of isomerization of electronically excited trans-stilbene and of the dissociation of isoquinoline-solvent
complexes in jet beams are compared with those expected from RRKM theory as a function of energy; the
comparison is made at low vibrational energies (~1200-3000 cm^(-1)). The jet result for the threshold energy
of the isomerization is compared with the activation energy for the reaction in solution. The two values are
in good agreement.