Target-selective photodegradation of oligosaccharides by a fullerene-boronic acid hybrid upon visible light irradiation.
Target-selective photodegradation of oligosaccharides by a fullerene-boronic acid hybrid upon visible light irradiation.
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DOI：
10.1039/c1cc15646b
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发表时间：
2011-10
影响因子：
4.9
通讯作者：
D. Takahashi;Shingo Hirono;K. Toshima
中科院分区：
文献类型：
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作者：
D. Takahashi;Shingo Hirono;K. Toshima
一种富勒烯衍生物不仅能在紫外光下降解低聚糖，还能在可见光下降解寡糖。此外，在中性条件下，设计合成了富勒烯-硼酸杂化材料，在没有任何添加剂的情况下，在可见光照射下，实现了低聚糖(β-D-半乳糖基呋喃糖苷)的目标选择性光降解。
A fullerene derivative was found to be capable of photodegrading oligosaccharides under irradiation with not only UV but also visible light. Furthermore, target-selective photodegradation of oligosaccharides (β-D-galactofuranosides) was achieved by a designed and synthesized fullerene-boronic acid hybrid upon irradiation with visible light in the absence of any additives under neutral conditions.