Aldehyde C-H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes
Aldehyde C-H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes
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DOI：
10.1039/b817263c
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发表时间：
2009-01-01
影响因子：
4
通讯作者：
Garralda, Maria A.
中科院分区：
文献类型：
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作者：
Garralda, Maria A.
这一观点侧重于后期过渡金属促进的醛C-H活化，包括螯合辅助反应。讨论了目前公认的不同金属配合物的反应机理、酰基氢氧根形成的反应活性以及过量试剂对进一步醛的催化反应。均相催化醛脱碳或二聚反应也进行了综述。
This perspective focuses on the aldehyde C-H activation promoted by late transition metals, including the chelation-assisted reactions. The mechanisms currently accepted for different metal complexes, the reactivity of acyl hydrido species formed, and the reactions promoted on further aldehyde when using excess reagent are discussed. Homogeneous catalytic aldehyde decarbonylation or dimerization reactions are also reviewed.