A Comprehensive Reaction Mechanism For Carbon Monoxide/Hydrogen/Oxygen Kinetics
A Comprehensive Reaction Mechanism For Carbon Monoxide/Hydrogen/Oxygen Kinetics
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DOI：
10.1080/00102209108951759
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发表时间：
1991-09
影响因子：
1.9
通讯作者：
R. Yetter;F. Dryer;H. Rabitz
中科院分区：
文献类型：
--
作者：
R. Yetter;F. Dryer;H. Rabitz
摘要 描述了在氢气存在下氧化一氧化碳的综合反应机理。将模型预测与各种物理条件下的实验数据进行比较。从激波管实验和各种类型的反应器实验中获得的数据包括 823-2870 K 的组合温度范围、0.0005 至 6.0 之间的燃料-氧化剂当量比、0005 至 128 之间的 C/H 比以及 0.3 至 2.2 个大气压之间的压力。通过模型预测和灵敏度分析计算再现实验结果，获得了反应机理的验证。 后面的计算提供了模型预测对上述整个实验参数范围内施加的输入参数的敏感性的定量测量。
Abstract A comprehensive reaction mechanism for the oxidation of carbon monoxide in the presence of hydrogen is described. Model predictions are compared with experimental data over wide ranges of physical conditions. The data, obtained from shock tube experiments and various types of reactor experiments, encompassed a combined temperature range of 823-2870 K, fuel-oxidizer equivalence ratios between 0.0005 and 6.0, C/H ratios between 0005 and 128, and pressures between 0.3 and 2.2 atmospheres, Validation of the reaction mechanism is obtained with reproduction of the experimental results by the model predictions and from sensitivity analysis calculations Results from the latter calculations provided a quantitative measure of the sensitivity of the model predictions to the imposed input parameters over the complete range of experimental parameters noted above.