A LC wireless passive temperature-pressure-humidity (TPH) sensor integrated on LTCC ceramic for harsh monitoring

A LC wireless passive temperature-pressure-humidity (TPH) sensor integrated on LTCC ceramic for harsh monitoring
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DOI:
10.1016/j.snb.2018.04.094
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发表时间:
2018-10-01
影响因子:
8.4
通讯作者:
Xiong, Jijun
Xiong, Jijun
中科院分区:
化学1区
文献类型:
--
作者:
Tan, Qiulin;Lv, Wen;Xiong, Jijun

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在本研究中,提出了一种基于低温共烧陶瓷(LTCC)技术的LC无线无源TPH传感器,用于苛刻的TPH监测。通过HFSS模拟对LC无线无源TPH传感器进行了框架优化,并采用丝网印刷技术、低温共烧工艺、亚胺化工艺在杜邦(R) 951 AT陶瓷上制备。利用扫描电镜(SEM)和傅里叶变换红外光谱(FT-IR)对制备的聚酰亚胺(PI)薄膜进行了显微镜和光谱学表征。实验结果表明,所制备的LC无线无源TPH传感器可以在25 ~ 200℃、70 ~ 220kpa、24 ~ 90% rh的环境下稳定工作,这得益于HFSS仿真优化和我们提出的解决TPH传感器相互关系的算法。压力传感器在64%RH、150℃、70-220 kPa环境下的频移为0.4875 MHz,灵敏度为3.25 kHz/kPa;温度传感器在64%RH、1 atm、25℃(室温)至200℃环境下的频移为1.6 MHz,灵敏度为9.143 kHz/℃。湿度传感器在RT、1 atm、24-90%RH环境下的频移约为7.23 MHz。在低湿度下实现了20 kHz/%RH的灵敏度,在高湿(60-90%RH)下实现了高达200 kHz/%RH的灵敏度。此外,所制备的PI膜对H2S、NH3、CH4具有很高的选择性,这对于一些恶劣环境(如化学医药合成、化学涂装)和矿山环境监测(经常存在CH4和H2S)具有重要意义。因此,本文提出的LC无线无源TPH传感器在变化范围广的TPH环境中表现出稳定的性能,适用于恶劣环境下的TPH同时监测。(C) 2018 Elsevier B.V.版权所有
In this study, a LC wireless passive TPH sensor based on low-temperature co-fired ceramic (LTCC) technology for harsh TPH monitoring was presented. The LC wireless passive TPH sensor was frame-optimized by performing HFSS simulations and fabricated on DuPont (R) 951 AT ceramic using the screen-printing technique, low-temperature co-fired process, imidization process. The microscopy and spectroscopy of as-prepared thin polyimide (PI) film were characterized by the dint of scanning electron microscope (SEM) and fourier transform infrared spectroscopy (FT-IR). The experimental tests indicate the as-prepared LC wireless passive TPH sensor can stably operate at an ambient environment of 25-200 degrees C, 70-220kPa, and 24-90%RH, which attributes to the HFSS simulation optimization and the algorithm we proposed for solving the interrelationship of TPH sensor. The frequency shift of the pressure sensor was 0.4875 MHz with a sensitivity of 3.25 kHz/kPa in the environment of 64%RH, 150 degrees C, 70-220 kPa, while the temperature sensor was 1.6 MHz, 9.143 kHz/degrees C in the environment of 64%RH, I atm, from 25 degrees C (room temperature, RT) to 200 degrees C. Moreover, the humidity sensor, which has the frequency shift of about 7.23 MHz at RT, 1 atm, 24-90%RH, realized a sensitivity of 20 kHz/%RH at low humidity and a sensitivity up to 200 kHz/%RH at high humidity( 60-90%RH). What's more, the as-prepared PI film is highly selective to H2S, NH3, CH4 which is significant for some harsh environments (e.g., chemical & medical synthesis and chemical painting) and mine environmental monitoring (where CH4 and H2S often exist). Therefore, the proposed LC wireless passive TPH sensor, which shows stable performance in a TPH environment with a wide range of variation, is suitable for simultaneous TPH monitoring in harsh environments. (C) 2018 Elsevier B.V. All rights reserved.