6,7,9,10-Tetra-hydro-16,22-ethano-oxyethano-5,8,11,19-tetra-oxa-16,22-diaza-dibenzo[h,q]cyclo-octa-decine-17,21-dione: a benzyl-annelated macrobicyclic diamide.
6,7,9,10-Tetra-hydro-16,22-ethano-oxyethano-5,8,11,19-tetra-oxa-16,22-diaza-dibenzo[h,q]cyclo-octa-decine-17,21-dione: a benzyl-annelated macrobicyclic diamide.
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6,7,9,10-四氢-16,22-乙醇-氧乙醇-5,8,11,19-四氧杂-16,22-二氮杂-二苯并[h,q]环-八-癸辛-
DOI：
10.1107/s1600536808030067
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发表时间：
2008
期刊：
影响因子：
--
通讯作者：
Taylor,RichardW
中科院分区：
文献类型：
--
作者：
Smith,GaryLN;Lei,Yang;Powell,DouglasR;Taylor,RichardW
大双环标题化合物C24H28N2O7具有两个叔二胺桥头原子，由一个12元环(N2O2给体集)和两个18元环(N2O4给体集)组成。固体结构表明，每个酰胺基团都不与邻苯环共面，核磁共振研究表明，这种构象关系在溶液中持续存在。
The macrobicyclic title compound, C24H28N2O7, has two tertiary diamide bridgehead atoms and is composed of a 12-membered ring (N2O2 donor set) and two 18-membered rings (N2O4 donor sets). The solid-state structure shows that each of the amide groups is not coplanar with the adjacent benzene ring and NMR studies indicate that this conformational relationship persists in solution.