Order and disorder in fullerene and fulleride solids
Order and disorder in fullerene and fulleride solids
复制标题
富勒烯和富勒化物固体的有序和无序
DOI：
10.1016/0022-3697(93)90287-2
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发表时间：
1993
影响因子：
4
通讯作者：
P. Heiney
中科院分区：
文献类型：
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作者：
J. Fischer;P. Heiney
综述了富勒烯固体C60、C60O和C70以及C60碱金属插层化合物的晶体结构和有序/无序现象。综述了在原始固体中定向熔化和淬灭定向无序的最新研究结果，并描述了微小扰动对准球形分子形状的影响。在石墨等其他主体晶格的背景下，讨论了C60的插层性质。根据对定向势的竞争贡献，富勒烯和富勒化物中的各种取向关联是合理的。碱金属富勒化物的结构性质与电子性质和超导电性有关，并描述了一种更新的二元相图。
A review is given of crystal structures and order/disorder phenomena in the fullerene solids C60, C60O and C70and in the alkali metal intercalation compounds of C60. Recent results on orientational melting and quenched orientational disorder in the pristine solids are summarized, and the effect of small perturbations on the quasi-spherical molecular shape are described. The intercalation properties of C60are discussed in the context of other host lattices such as graphite. The variety of orientational correlations in fullerenes and fullerides is rationalized in terms of competing contributions to the orientational potentials. Structural properties of alkali fullerides are correlated with electronic properties and superconductivity, and an updated binary phase diagram is described.
Terasawa, T.，“无碰撞等离子体中开尔文-亥姆霍兹不稳定性中的异常离子混合”，Phys Rev. Letters。
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