MALYNGAMIDES-D AND MALYNGAMIDES-E, 2 TRANS-7-METHOXY-9-METHYLHEXADEC-4-ENAMIDES FROM A DEEP-WATER VARIETY OF MARINE CYANOPHYTE LYNGBYA-MAJUSCULA
MALYNGAMIDES-D AND MALYNGAMIDES-E, 2 TRANS-7-METHOXY-9-METHYLHEXADEC-4-ENAMIDES FROM A DEEP-WATER VARIETY OF MARINE CYANOPHYTE LYNGBYA-MAJUSCULA
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DOI：
10.1021/jo00416a022
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发表时间：
1978-01-01
影响因子：
3.6
通讯作者：
MOORE, RE
中科院分区：
文献类型：
--
作者：
MYNDERSE, JS;MOORE, RE
从L. majuscula。详细的光谱分析，主要是NMR和化学降解，分别揭示了马林酰胺D和E的总体结构（2和3）。马林酰胺D和E在乙酰化时产生相同的二乙酸酯。2和3的环立体化学由NMR和化学反应性数据定义。
Malyngamides D and E were isolated from the lipid extract of L. majuscula. Detailed spectral analysis, mostly NMR and chemical degradation, revealed the gross structures (2 and 3) of malyngamides D and E, respectively. Malyngamides D and E produce the same diacetate on acetylation. The ring stereochemistry of 2 and 3 was defined from NMR and chemical reactivity data.