Synthese und Struktur des ersten dreigliedrigen Arsen—Phosphor—Platin-Ringes / Synthesis and Structure of the First Three-Membered Ring Containing Arsenic, Phosphorus and Platinum

Synthese und Struktur des ersten dreigliedrigen Arsen—Phosphor—Platin-Ringes / Synthesis and Structure of the First Three-Membered Ring Containing Arsenic, Phosphorus and Platinum
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第一个含砷、磷、铂三元环的合成与结构

DOI:
10.1515/znb-1988-0504
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发表时间:
1988
期刊:
Zeitschrift für Naturforschung B
影响因子:
--
通讯作者:
P. Jones
P. Jones
中科院分区:
--
文献类型:
--
作者:
F. Edelmann;C. Spang;H. Roesky;P. Jones

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在DBU存在下,2,4,6-三丁基苯基膦与CpFe(C5 H4 AsCl 2)反应生成CpFe[C5 H4 As = PC6 H2(t-Bu)3]。砷膦与(Ph 3 P)2 PtC 2 H4反应生成一个含有砷、磷和铂的三元环。
2,4,6-Tri-butylphenylphosphane reacts with CpFe(C5H4AsCl2) in the presence of DBU to yield CpFe[C5H4As=PC6H2(t-Bu)3]. The reaction of this arsaphosphene with (Ph3P)2PtC2H4 yields , a three-membered ring containing arsenic, phosphorus and platinum.