Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire.
Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire.
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访问高密度三足配体的低密度配位模式以完成其配位库。
DOI：
10.1039/c2dt31061a
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发表时间：
2012
影响因子：
4
通讯作者：
Stuart D. Robertson
中科院分区：
文献类型：
--
作者：
T. Cadenbach;Eva Hevia;A. Kennedy;R. Mulvey;Janie;Stuart D. Robertson
合成并研究了中性三脚架四胺Me（6）TREN与tBu（3）Ga或tBu（2）Zn的新配合物，其分子结构首次揭示了它们与金属中心以η（1）或η（2）模式配位，增加了先前报道的η（3）和η（4）配位实例。
New coordination complexes of the neutral tripodal tetra-amine Me(6)TREN with tBu(3)Ga or tBu(2)Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an η(1) or η(2) mode, adding to previously reported η(3) and η(4) ligated examples.