Solution and Crystal Structure of a Hexacoordinate Phosphoranate Bearing Two Martin Ligands and Two Methyl Groups
Solution and Crystal Structure of a Hexacoordinate Phosphoranate Bearing Two Martin Ligands and Two Methyl Groups
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DOI：
10.1080/10426500902718265
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发表时间：
2009-03
期刊：
影响因子：
--
通讯作者：
S. Matsukawa;Yohsuke Yamamoto;K. Akiba
中科院分区：
文献类型：
--
作者：
S. Matsukawa;Yohsuke Yamamoto;K. Akiba
通过带有羟基的单环正膦与KH反应合成带有两个Martin配体和两个甲基的六配位磷酸酯，并在18-冠-6醚存在下结晶。正膦酸酯的晶体结构可以被视为O-赤道甲基正膦与甲基阴离子反应的中间模型。
A hexacoordinate phosphoranate bearing two Martin ligands and two methyl groups was synthesized by the reaction of the monocyclic phosphorane bearing a hydroxy group with KH, and was crystallized in the presence of 18-crown-6 ether. The crystal structure of the phosphoranate could be regarded as an intermediate model in the reaction of the O-equatorial methylphosphorane with a methyl anion.