Polymer-supported ferrocenyl oxazolines for the catalyzed highly enantioselective phenyl transfer to aldehydes
Polymer-supported ferrocenyl oxazolines for the catalyzed highly enantioselective phenyl transfer to aldehydes
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DOI：
10.1016/s0960-894x(02)00271-8
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发表时间：
2002-07-22
影响因子：
2.7
通讯作者：
Muñiz, K
中科院分区：
文献类型：
--
作者：
Bolm, C;Hermanns, N;Muñiz, K
合成了一种新的手性MeO-PEG固载二茂铁基恶唑啉，并成功地应用于对映选择性的苯基转移反应。产物以高产率和优异的对映选择性（高达97%ee）获得。此外，二茂铁的回收是容易的，并且在随后的反应中保持催化剂效率。(C)2002爱思唯尔科技有限公司版权所有。
A new chiral MeO-PEG-supported ferrocenyl oxazoline was synthesized and successfully employed in the enantioselective phenyl transfer to aldehydes. The products were obtained in high yields and with excellent enantioselectivities (up to 97% ee). Furthermore, the recovery of the ferrocene was facile, and catalyst efficiency was maintained in subsequent reactions. (C) 2002 Elsevier Science Ltd. All rights reserved.