Many faces of dipyrrins: from hydrogen-bonded networks to homoand heteronuclear metallamacrocycles

Many faces of dipyrrins: from hydrogen-bonded networks to homoand heteronuclear metallamacrocycles
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DOI:
10.1021/ic701949k
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发表时间:
2008-02-04
影响因子:
4.6
通讯作者:
Hosseini, Mir Wais
Hosseini, Mir Wais
中科院分区:
化学2区
文献类型:
--
作者:
Salazar-Mendoza, Domingo;Baudron, Stephane A.;Hosseini, Mir Wais

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两性5-(4-氰基苯基)二吡咯配体,提供三种不同的状态,即,阳离子、中性和阴离子,已被用于形成1-D氢键网络在其质子化的形式和均和异双核金属大环,分别在其中性和去质子化的状态,具有各种配位模式。
The amphoteric 5-(4-cyanophenyl)dipyrrin ligand, offering three distinct states, i.e., cationic, neutral, and anionic, has been exploited for the formation of a 1-D hydrogen-bonded network in its protonated form and both homo- and heterobinuclear metallamacrocycles, in its neutral and deprotonated states, respectively, with a variety of coordination modes.