Highly Substituted Cyclopentenes Formation via a Stereoselective Tandem CDC Reaction and Cyclization
Highly Substituted Cyclopentenes Formation via a Stereoselective Tandem CDC Reaction and Cyclization
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DOI：
10.1002/cjoc.201200951
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发表时间：
2012-12
影响因子：
5.4
通讯作者：
Yi Li;Li Cao;Xiaoyan Luo;W. Deng
中科院分区：
文献类型：
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作者：
Yi Li;Li Cao;Xiaoyan Luo;W. Deng
通过ddq介导的(E)-1,2-二芳基丙烷-1烯的交叉脱氢均偶联，建立了一种易催化的铁催化的C(sp3)-C（sp2）键，用于合成高芳基取代的环戊烯。
A facile iron-catalyzed C(sp3)-C(sp2) bond formation through DDQ-mediated cross-dehydrogenative homo-coupling of (E)-1,2-diarylprop-1-enes for the synthesis of highly aryl-substituted cyclopentenes has been developed.